Espectroscopía de impedancia eléctrica y dieléctrica aplicada en el control de calidad de aceites minerales. Revisión del estado del arte
DOI:
https://doi.org/10.26507/paper.2932Palabras clave:
aceite mineral, impedancia, eléctrica, dieléctrica, control de calidadResumen
La espectroscopía de impedancia es una técnica que junto a la espectroscopía dieléctrica, facilitan una caracterización rápida y no destructiva de materiales biológicos, minerales y bioquímicos. El aceite mineral orgánico e inorgánico se obtiene como un subproducto del procesamiento del petróleo crudo y es un ingrediente común en muchos productos cosméticos y normalmente usado como lubricante y aceite aislante. En el presente trabajo se realiza una exhaustiva revisión de la literatura sobre el uso de la espectroscopía de impedancia eléctrica y dieléctrica aplicada en el control de calidad de aceites minerales dado que es una técnica rápida y económica, además, es posible el uso de sensores de impedancia en los sitios de producción de aceite, donde, sería deseable conocer las principales características para una correcta clasificación del producto. Debido a lo anterior, la presente revisión tuvo como objetivo recopilar información científica publicada entre 1992 y 2022, que describe el uso de las técnicas de espectroscopia de impedancia eléctrica y dieléctrica en el control de calidad de los aceites minerales. En la revision se encontró el 40% de artículos con un enfoque respecto a la determinación de nuevas aplicaciones, un 41% respecto a la determinación de componentes y un 20% de la estabilidad del aceite, teniendo en cuenta que las propiedades eléctricas y la estabilidad térmica de los materiales aislantes están estrechamente relacionadas y las propiedades eléctricas se deterioran a medida que disminuye la estabilidad térmica del material, en diversos estudios se demostró que a medida que el aceite mineral se degrada, la conductividad aumenta debido al aumento en la concentración de especies conductoras tales como ácido nítrico (productos derivados de la oxidación) y contaminantes (por ejemplo, desgaste metálico partículas, agua). Los resultados sugieren que la medición en línea de la acidez del aceite es un importante factor de control de la calidad que podría realizarse en los motores de combustión, como complemento de los métodos convencionales de control del estado del aceite (por ejemplo, control del nivel y la presión del aceite). En resumen, propiedades eléctricas tales como permitividad, impedancia y conductividad proporcionan un medio prometedor para evaluar la calidad de estos aceites.
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