Evaluation of the effect of using carbon quantum dots as additives to commercial diesel on combustion parameters

Authors

  • Juan David Luna Lasso Institución Universitaria Pascual Bravo
  • Anderson Gallego Montoya Institución Universitaria Pascual Bravo
  • Karen Paola Cacúa Madero Institución Universitaria ITM
  • Bernardo Argemiro Herrera Múnera Institución Universitaria ITM

DOI:

https://doi.org/10.26507/paper.4717

Keywords:

puntos cuánticos de carbono (CQDs), retraso en la ignición, tasa de combustión, temperatura de combustión, técnica shadowgraph, microexplosiones, óxidos de nitrógeno

Abstract

Diesel fuel has played a fundamental role in economic development, powering critical sectors such as freight transportation, power generation, and heavy machinery. However, diesel engines pose significant environmental challenges due to the emission of particulate matter (PM) and gaseous pollutants, including carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxides (NOx). These concerns have driven the pursuit of alternative strategies aimed at minimizing environmental impact while maintaining combustion efficiency. In this context, carbon-based nanomaterials—particularly carbon quantum dots (CQDs) have emerged as promising additives. CQDs have the potential to enhance fuel reactivity, increase combustion rates, shorten ignition delay, and elevate combustion temperatures. This study investigates the effects of CQD/n-butanol dispersions in diesel fuel at concentrations of 50 mg/L and 100 mg/L. A single-droplet combustion system, combined with shadowgraph optical techniques, was employed to analyze critical parameters, including ignition delay, combustion temperature, burning rate, and micro-explosion formation. The results demonstrate that the addition of CQDs led to a reduction in ignition delay compared to conventional diesel and significantly promoted the occurrence of micro-explosions. This phenomenon facilitates improved air–fuel mixing and promotes more complete combustion. These findings suggest that CQDs represent a viable strategy for reducing pollutant emissions from diesel engines without compromising engine performance, thereby supporting a more sustainable energy transition as alternative technologies continue to mature.

References

Abdul Rasid, A. F., & Zhang, Y. (2021). Comparison of the burning of a single diesel droplet with volume and surface contamination of soot particles. Proceedings of the Combustion Institute, 38(2), 3159–3166. https://doi.org/10.1016/j.proci.2020.07.092

Bhumula, K. B., & Kumar, G. N. (2025). Effect of fuel injection timing on engine characteristics with an equal volume of 1-heptanol/diesel blend in a CRDI CI engine. Results in Engineering, 104632. https://doi.org/10.1016/j.rineng.2025.104632

Bitire, S. O., Nwanna, E. C., & Jen, T. C. (2023). The impact of CuO nanoparticles as fuel additives in biodiesel-blend fuelled diesel engine: A review. Energy and Environment, 34(7), 2259–2289. https://doi.org/10.1177/0958305X221089217

Castrejón-García, R., Castrejón-Pita, J. R., Martin, G. D., & Hutchings, I. M. (2011). The shadowgraph imaging technique and its modern application to fluid jets and drops (Vol. 57, Issue 3).

Değirmenci, H., Küçükosman, R., & Alper Yontar, A. (2024). An experimental study on droplet-scale combustion and atomization behavior in pure ethanol, methanol, and trimethyl borate, and their blends. Fuel, 357, 129716. https://doi.org/10.1016/j.fuel.2023.129716

Diego Aranda Ibáñez Director Javier Ballester Castañer Codirector Álvaro Muelas Expósito, A. (2021). Trabajo Fin de Máster Nueva metodología de formulación de surrogates de combustibles líquidos. Aplicación a combustible diésel. http://zaguan.unizar.es

EL-Seesy, A. I., & Hassan, H. (2019). Combustion characteristics of a diesel engine fueled by biodiesel-diesel-n-butanol blend and titanium oxide additives. Energy Procedia, 162, 48–56. https://doi.org/10.1016/j.egypro.2019.04.006

Gallego, A., Cacua, K., Gamboa, D., Rentería, J., & Herrera, B. (2023). Ignition Delay and Burning Rate Analysis of Diesel–Carbon Nanotube Blends Stabilized by a Surfactant: A Droplet-Scale Study. Energies, 16(23). https://doi.org/10.3390/en16237740

Gan, Y., & Qiao, L. (2011). Combustion characteristics of fuel droplets with addition of nano and micron-sized aluminum particles. Combustion and Flame, 158(2), 354–368. https://doi.org/10.1016/j.combustflame.2010.09.005

Gurgen, S., Unver, B., & Altin, I. (2017). Experimental investigation on cyclic variability, engine performance, and exhaust emissions in a diesel engine using alcohol-diesel fuel blends. Thermal Science, 21, 581–589. https://doi.org/10.2298/TSCI161020306G

Heidari-Maleni, A., Mesri Gundoshmian, T., Jahanbakhshi, A., & Ghobadian, B. (2020). Performance improvement and exhaust emissions reduction in diesel engine through the use of graphene quantum dot (GQD) nanoparticles and ethanol-biodiesel blends. Fuel, 267(January), 117116. https://doi.org/10.1016/j.fuel.2020.117116

Küçükosman, R., Yontar, A. A., & Ocakoglu, K. (2022). Nanoparticle additive fuels: Atomization, combustion and fuel characteristics. Journal of Analytical and Applied Pyrolysis, 165, 105575. https://doi.org/10.1016/j.jaap.2022.105575

M, D. DE, Motores T, A. Y., por, R., Luis Daniel Zapata Pemberthy Dirigida por, D., & José Vicente Pastor Soriano Valencia, D. (2010). Universidad politécnicapolit´politécnica de valencia.

Mei, D., Fang, Y., Zhang, D., Guo, D., & Chen, Z. (2023). Evaporation and micro-explosion performances of nano-fuel droplets. Fuel, 334. https://doi.org/10.1016/j.fuel.2022.126623

Nour, M., Attia, A. M. A., & Nada, S. A. (2019). Improvement of CI engine combustion and performance running on ternary blends of higher alcohol (Pentanol and Octanol)/hydrous ethanol/diesel. Fuel, 251, 10–22. https://doi.org/10.1016/j.fuel.2019.04.026

Ooi, J. B., Ismail, H. M., Swamy, V., Wang, X., Swain, A. K., & Rajanren, J. R. (2016). Graphite Oxide Nanoparticle as a Diesel Fuel Additive for Cleaner Emissions and Lower Fuel Consumption. Energy and Fuels, 30(2), 1341–1353. https://doi.org/10.1021/acs.energyfuels.5b02162

Pastor, J. V., Payri, R., Garcia-Oliver, J. M., & Briceño, F. J. (2013). Schlieren Methodology for the Analysis of Transient Diesel Flame Evolution. SAE International Journal of Engines, 6(3), 1661–1676. https://doi.org/10.4271/2013-24-0041

Revista_de_Sistemas_Experimentales_V4_N11_2. (n.d.). https://www.ecorfan.org/bolivia/researchjournals/Sistemas_Experimentales/vol4num11/Revista_de_Sistemas_Experimentales_V4_N11_2.pdf

Sánchez Barboza, L., & Vásquez Stanescu, C. (n.d.). Revista científica ecociencia combustibles fósiles para generar energía. efficiency of developed countries in controlling the use of fossil fuels to generate energy (Vol. 4, Issue 2).

Singh, G., Esmaeilpour, M., & Ratner, A. (2020). Effect of carbon-based nanoparticles on the ignition, combustion and flame characteristics of crude oil droplets. Energy, 197. https://doi.org/10.1016/j.energy.2020.117227

Zapata-Hernandez, C., Durango-Giraldo, G., Gomez-Echeverri, M., Buitrago-Sierra, R., Herrera, B., & Cacua, K. (2024). The impact of carbon quantum dots derived from spent coffee grounds on the droplet combustion of diesel/n-butanol blend. Heliyon, 10(21). https://doi.org/10.1016/j.heliyon.2024.e39671

How to Cite

[1]
J. D. Luna Lasso, A. Gallego Montoya, K. P. Cacúa Madero, and B. A. Herrera Múnera, “Evaluation of the effect of using carbon quantum dots as additives to commercial diesel on combustion parameters”, EIEI ACOFI, Sep. 2025.

Downloads

Download data is not yet available.

Published

2025-09-08

Proceeding

Section

Energía: transición, eficiencia y seguridad
Article metrics
Abstract views
Galley vies
PDF Views
HTML views
Other views
Escanea para compartir
QR Code
Crossref Cited-by logo